摘要本文阐述了硝基氯苯废水的来源及特点,并总结了现有的氯代硝基苯类废水处理技术。通过控制反应器的外加电场电压等参数,探索最优运行条件;利用紫外图谱、液相色谱、质谱等检测手段,分析中间产物,结合参考文献,推断硝基氯苯的厌氧降解机理;通过分析进出水水质毒性,评价该技术的先进性。研究发现,电场环境有利于目标降解物的还原及脱氯。由急性毒性测试可知,在经过UASB或BES-UASB处理之后,硝基氯代化合物转化为氨基化合物,目标污染物的结构发生了较大的改变,与原水相比毒性大幅度的降低。实验结果表明电生物反应器对硝基氯苯废水有较为理想的的降解和生化性改善的效果63818
毕业论文关键词 电生物反应器;硝基氯苯废水;外加电场电压;急性毒性测试
毕业设计说明书(论文)外文摘要
Title Electric Biological Reactor for Degradation of Nitrochlorobenzene Containing Wastewater
Abstract This paper describes the sources and characteristics of nitrochlorobenzene wastewater,and summarizes existing nitrochlorobenzene wastewater treatment technology. Via controling of reactor parameters such as the applied electric field voltage, to explore the optimal operation conditions. By using UV spectrum, liquid chromatography, mass spectrometry and other detection methods, analysising of the intermediate products and combining with references, to infer the mechanism of anaerobic degradation of nitrochlorobenzene. Advanced of the technology was evaluated by means of analysising the toxicity of yielding water. It was founded that electric field environment favored the reduction and dechlorination of the degradation. The acute toxicity test showed that notri chloro compunds are converted into amino compounds after the treatment of UASB or BES-UASB, and the structure of target pollutants changes and the toxicity of the raw water decreases greatly. The results of experiment indicated that electric bioreactor responses to nitrochlorobenzene wastewater could achieved a result with ideal degradation and biological treatability improvement.
Keywords electric bioreactor; nitrochlorobenzene wastewater; applied electric field voltage; acute toxicity test
1 绪论 1
1.1 序言 1
1.1.1 氯代硝基苯类废水的来源及污染 2
1.1.2 氯代硝基苯类废水的危害 2
1.1.3 氯代硝基苯类废水的特点 2
1.2 氯代硝基苯类废水处理技术 2
1.2.1 物理处理技术 2
1.2.2 化学氧化还原处理技术 3
1.2.3 生物降解处理技术 3
1.2.2 耦合处理技术 3
1.3 本论文的选题意义 3
1.4 研究工作主要内容 6
2 实验 7
2.1 实验药品及仪器 7
2.1.1 实验药品 2
2.1.2 实验仪器 2
2.2 实验装置与方法 7
2.2.1 UASB反应器的设计及搭建 2
2.2.2 反应器的启动 2
2.3 分析与测试方法